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intramolecular coupling

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  • Manganese-mediated coupling reactions — are radical coupling reactions between enolizable carbonyl compounds and unsaturated compounds initiated by a manganese(III) salt, typically manganese(III) acetate. Copper(II) acetate is sometimes used as a co oxidant to assist in the oxidation… …   Wikipedia

  • Pinacol coupling reaction — A pinacol coupling reaction is an organic reaction in which a carbon carbon covalent bond is formed between the carbonyl groups of an aldehyde or a ketone in presence of an electron donor in a free radical process Ref|1. The reaction product is a …   Wikipedia

  • Single-molecule magnet — Single molecule magnets or SMMs are a class of metalorganic compounds, that show superparamagnetic behavior below a certain blocking temperature at the molecular scale. In this temperature range, SMMs exhibit magnetic hysteresis of purely… …   Wikipedia

  • Cyclopropane — Cyclopropane[1] …   Wikipedia

  • organosulfur compound — ▪ chemical compound Introduction also spelled  organosulphur compound , also called  organic sulfur compound   a subclass of organic substances that contain sulfur and that are known for their varied occurrence and unusual properties. They are… …   Universalium

  • Disilene — Disilenes Disilenes are compounds containing a silicon–silicon double bond and are considered to be heavier analogues of alkenes. They are sometimes also called disilaalkenes. Contents 1 History …   Wikipedia

  • Galanthamine total synthesis — ; 2006; 106(1) pp 116 133; (Review) DOI|10.1021/cr040415t] The natural source of galantamine are certain species of daffodil and because these species are scarce and because the isolation of galanthamine from daffodil is expensive (a 1996 figure… …   Wikipedia

  • Organopalladium — chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions. Palladium is often used as a catalyst in the reduction of alkenes and alkynes with hydrogen. This process involves the formation of …   Wikipedia

  • Oligonucleotide synthesis — is the chemical synthesis of relatively short fragments of nucleic acids with defined chemical structure (sequence). The technique is extremely useful in current laboratory practice because it provides a rapid and inexpensive access to custom… …   Wikipedia

  • Alkyne trimerisation — An alkyne trimerisation reaction is a 2+2+2 cyclization reaction in which three alkyne molecules react to form an aromatic compound. The reaction is pseudo pericyclic since it has not been observed to occur without the assistance of metal… …   Wikipedia

  • Ugi reaction — The Ugi reaction is a multi component reaction in organic chemistry involving a ketone or aldehyde, an amine, an isocyanide and a carboxylic acid to form a bis amide. [cite journal | author = Ugi, I; Meyr, R.; Fetzer, U.; Steinbrückner, C. title …   Wikipedia

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